Barcelona began to believe in the impossible dream of clawing back their shock 4-0 loss from the first leg when Luis Suarez headed over the line in the third minute and a Layvin Kurzawa own goal gave them further hope before the break.
Lionel Messi’s penalty five minutes into the second period had the Nou Camp on its feet but Cavani’s strike in the 62nd was a sucker punch to Barca’s ambitions from which Luis Enrique’s side took a while to recover.
A curled free kick from Neymar in the 88th minute gave them hope and the Brazilian converted a penalty before substitute Roberto slid in to knock the ball beyond Kevin Trapp from a chipped free kick and send Barca through to the last eight.
An electric atmosphere gripped the Nou Camp before kick-off after Suarez and Luis Enrique had said they truly believed a comeback was on and the players caught the wave of optimism by swarming all over PSG from the first whistle.
Trapp struggled to cope with the early pressure and flapped at a high ball, allowing Suarez to jump ahead of him and force the ball over the line.
PSG had a penalty appeal turned down when Julian Draxler’s low cross struck Javier Mascherano’s arm but it was one of few forays forward from PSG in the first half as Barca did all the attacking.
The Catalans owed their second to another piece of slack defending, however, as Iniesta nudged his way past Marquinhos in the area to knock the ball back into the danger zone and it bounced off the swinging leg of Kurzawa and into the far corner.
Firstly, Cavani should have had his second as he was played in by Draxler, but this time Marc-Andre ter Stegen stood up to block with an outstretched leg.
PSG's two-goal hero from the first Angel di Maria had started on the bench, but the former Real Madrid man should have rubbed salt in Barca's wounds five minutes from time when he somehow skewed wide with just Ter Stegen to beat.
Just when Barca looked down and out Neymar restored hope when he curled home a sensational free-kick high into the top corner.
And as the match entered stoppage time, Barca were awarded a second controversial penalty when Suarez tumbled under a challenge form Marquinhos.
Neymar this time took responsibility to send Trapp the wrong way.
And the Brazilian also showed a cool head amongst a mad final minute when he cut inside before chipping into the box for substitute Roberto to extend his right leg just enough to beat Trapp and leave PSG floored.
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